Gas sensor arrays are versatile and powerful tools for gas detection and analysis, enabling a wide range of applications across numerous industries. Critically, the accuracy and reliability of these arrays depend on the distinct gas sensing behavior or selectivity of the individual component gas sensors. However, studies of such arrays often consider only overly idealized scenarios, and the interaction between gas molecules is not typically considered in such studies. Here, based on first-principles calculations and direct experimental demonstrations, we show that interactions between gas molecules at the surface can play a significant role. We found that NO