Enantioselective Cobalt-Catalyzed Remote Hydroboration of Alkenylboronates.

• Tác giả: Anbang Bai, Wenke Dong, Peiwen Han, Jingyi He, Chenchen Li, Zheming Liu, Xiaoyu Zhang
• Ngôn ngữ: eng
• Thông tin xuất bản: United States : Organic letters , 2025
• Bộ sưu tập: NCBI
• ID: 56581

Tóm tắt

Heteroatomic groups in alkenes typically direct thermodynamically favored chain walking of C═C bonds toward themselves, thereby facilitating C-H bond functionalization near the heteroatoms. We present herein an efficient cobalt-catalyzed contra-thermodynamic remote hydroboration of alkenylboronates with pinacolborane to synthesize chiral 1,