In order to increase the energy density and improve the cyclability of lithium-sulfur (Li-S) batteries, a combined strategy is devised and evaluated for high-performance Li-S batteries. It consists of the following steps to reduce the loss of active sulfur and sulfides migrating in the liquid electrolyte to the anode and add electrocatalyst groups in the cathode or catholyte: (i) A hollow porous nanoparticle coating cathode host with a pseudocapacitive PEDOT:PSS binder that also contributes to trapping polysulfides. (ii) A thin interlayer of B-N-graphene (BNG) nanoplatelets on the above cathode trapping polysulfides while participating in the electron transfer and acting as an electrocatalyst, thus ensuring that the trapped sulfides remain active in the cathode. (iii) Added semiconductor phthalocyanine VOPc or CoPc to form an electrocatalyst network in the catholyte, trapping polysulfides and promoting their redox reactions with Li