Boosting Tin Perovskite Solar Cell Performance via Light-Induced Interface Doping.

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Tác giả: Yuangan Chen, Honghe Ding, Zachary Fink, Junyao Gao, Qin Hu, Yu Li, Yuan Li, Tianyu Liu, Deying Luo, Huimin Meng, Thomas P Russell, Mulin Sun, Xuefei Wu, Fang Xiang, Zhengguo Xiao, Hao Xu, Zhenzhu Zhao, Junfa Zhu

Ngôn ngữ: eng

Ký hiệu phân loại: 636.0885 Animal husbandry

Thông tin xuất bản: United States : Nano letters , 2025

Mô tả vật lý:

Bộ sưu tập: NCBI

ID: 57288

Continuous breakthroughs have been achieved in the photoelectric conversion efficiency (PCE) of tin-based perovskite solar cells (TPSCs) in recent years. Inspired by performance improvements observed during device storage, we identified beneficial light-induced interface doping (LIID) in the TPSCs. In situ analyses using X-ray photoelectron spectroscopy and ultraviolet photoelectron spectroscopy reveal that ion migration and oxidation at the interface induce beneficial doping effects, enhancing carrier transport and significantly boosting device performance. By implementing specific illumination techniques or maximum power point tracking (MPPT) methods to achieve LIID, we increased the open-circuit voltage while maintaining a high short-circuit current, reaching a PCE of up to 14.91%. Furthermore, this efficiency was sustained at 70% of its maximum value after nearly 900 h of continuous operation. Our study introduces a novel approach to addressing energy band mismatch, paving the way for improved efficiency in tin-based perovskite solar cells.
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