Enhanced oxygen evolution reaction through improved lattice oxygen activity via carbon dots incorporation into MOFs.

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Tác giả: Delun Chen, Hai Li, Weiwei Li, Zhun Tang, Jinchun Tu, Bingrong Wang, Rentong Yu, Xiaolin Zhang

Ngôn ngữ: eng

Ký hiệu phân loại: 968.91 *Zimbabwe

Thông tin xuất bản: United States : Journal of colloid and interface science , 2025

Mô tả vật lý:

Bộ sưu tập: NCBI

ID: 61058

Emerging of the lattice oxygen mechanism (LOM) provides a new opportunity for enhancing oxygen evolution reaction (OER) activity. However, its stability suffers from metal cation dissolution and lattice oxygen anionic redox chemistry. In this paper, carbon dots (CDs)-modified nickel-iron MOF (Metal-Organic Framework) nanosheets (NiFe-BDC/CDs) were prepared for efficient OER electrocatalysis. The introduction of CDs promotes the hybridization of the O 2p band in the MOF with the metal 3d band near the Fermi level, leading to improved involvement of lattice oxygen in the oxygen evolution reaction. Additionally, C-M bonds formed between CDs and metal sites in MOF enhanced the stability of electrocatalyst. As results, the prepared NiFe-BDC/CDs electrodes demonstrated a current density of 100 mA cm
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