Load bearing/energy storage integrated devices (LEIDs) featuring cementitious electrolytes have become ideal for large-scale energy storage. Nevertheless, the progression of LEIDs is still in its nascent phase and considerable endeavors concerning cementitious electrolytes and electrode materials are necessary to further boost the charge storage ability. Here, we propose a facile synchronous reaction method for preparing sodium acrylate (SA)-based in-situ polymerized cementitious electrolyte. The soft polymer network and hard cement matrix are interwoven together. The resulting cementitious electrolyte not only exhibits improved mechanical properties (flexural strength of 14.7 MPa and compressive strength of 44.7 MPa), but also possesses enhanced ionic conductivity (26.7 mS cm