Construction of near-infrared gradient hydrogel actuators using self-floating induction and LED photopolymerization.

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Tác giả: Yanjing Gao, Jun Nie, Fang Sun, Mengyuan Tian

Ngôn ngữ: eng

Ký hiệu phân loại: 354.94 Labor in specific extractive, manufacturing, construction occupations

Thông tin xuất bản: United States : Journal of colloid and interface science , 2025

Mô tả vật lý:

Bộ sưu tập: NCBI

ID: 61601

Creating gradient hydrogels for remote control of bionic systems continues to be challenging due to the complexity of the preparation process. Herein, we have proposed a strategy to prepare near-infrared photothermal conversion gradient hydrogel featuring self-floating-induced gradient structures through fast LED light-triggered photopolymerization. A judiciously designed polysiloxane acrylate crosslinker (PA-Si) possesses the self-floating, crosslinking, and initiating properties. The self-floating ability of the PA-Si enables the autonomous formation of compositional and crosslinking gradients within the hydrogel, resulting in top-down variations in contraction stress. The gradient hydrogel demonstrates excellent NIR light-driven response (50°/s), cyclic stability, and mechanical properties (4392.84 kJ/m
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