From the methanol extract of Tetrastigma erubescens Planch. eight compounds: methyl 3,6-anhydro-2-deoxy-beta-D-furanoside (1), beta-sitosterol (2), stigmasterol (3), daucosterol (4), (-)-lyoniresinol 3alpha-O-beta-D-glucopyranoside (5), Nbenzoyl-2-aminoethyl-beta-D-glucopyranoside (6), benzylalcoholglucoside (7), and 2-(1,2-dihydroxylethyl) furan (8) were isolated by various chromatography methods. Their chemical structures were elucidated by ESI-MS, HR-ESI-MS, 1D, 2D NMR experiments and in comparison with previous reported data. Among them, methyl 3,6-anhydro-2-deoxy-beta-D-furanoside (1) and N-benzoyl-2-aminoethyl-beta-D-glucopyranoside (6) were isolated for the first time from nature.