From methanol extracts of the plant on the ground verbena (Verbena officinal is L.) a sesquitecpen compound new glycoside 12-hydroxynerolidol 12-0-[Beta-D-xylopyranosyl-(l ~ 2) - Beta-Dglucopyranoside], be named verbenaside A (I) together with four iridoid compounds 6 Beta-hydroxyipolamiide (2), ipolamiide (3), verbenaloside (4), hastatoside (5), 3-phenyl compound propanoit phenyl compounds propanoid martynoside(6), acteoside (7) and verbasoside (8) have been isolated by chromatographic methods combined. Its chemical structure was determined by modern spectroscopic methods such as mass spectrometry ESI-MS, nuclear magnetic resonance spectra of one-dimensional (1D-NMR: 1 H, 13C-NMR spectrum and DEPT 90, DEPT 135) and two-dimensional (2D-NMR: HSQC and HMBC) and compared with the general facts have been published.