Covalently Coupling Carbon Quantum Dots for Photoluminescence Red Shift Response to pH.

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Tác giả: Jie-Yao Song, Jun-Ru Tian, Zhongchang Wang

Ngôn ngữ: eng

Ký hiệu phân loại:

Thông tin xuất bản: United States : Inorganic chemistry , 2025

Mô tả vật lý:

Bộ sưu tập: NCBI

ID: 642540

Conventional fluorescent pH sensors, despite offering high sensitivity and rapid response, are limited by their reliance on fluorescence intensity changes, hindering applications requiring precise wavelength control. Here, we present a pH sensing strategy based on cross-linked carbon quantum dots (CCL-CQDs) displaying a remarkable pH-dependent red shift in the fluorescence emission wavelength. Amino- and carboxyl-functionalized CQDs were synthesized via a one-step hydrothermal method and further assembled into CCL-CQDs through the condensation reaction between amino groups and glutaraldehyde. The CCL-CQDs displayed excellent pH sensitivity, with their fluorescence emission wavelength exhibiting a linear red shift upon increasing pH (from 2.29 to 7.16). The results of mechanism exploration revealed that H
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