Alkaline phosphatase-mediated hydrolysis of dissolved organic phosphorus enhances phosphorus cycling in the Yellow Sea.

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Tác giả: Xiaokun Ding, Huiwang Gao, Xinyu Guo, Haoyu Jin, Lei Lin, Jie Shi, Aobo Wang, Xiaohong Yao, Chao Zhang

Ngôn ngữ: eng

Ký hiệu phân loại: 572.553 +Phosphorus

Thông tin xuất bản: England : Environmental pollution (Barking, Essex : 1987) , 2025

Mô tả vật lý:

Bộ sưu tập: NCBI

ID: 643929

The utilization of dissolved organic phosphorus (DOP) driven by alkaline phosphatase hydrolysis contributes significantly to mitigating coastal nitrogen pollution through alleviating phosphorus (P) limitation. However, the lack of a parameterization for this process limits the quantitative assessment of its impact on marine nutrient pollution and cycling. Our study addresses this issue using data from a series of on-board microcosm experiments conducted in the Yellow Sea, where P limitation prevails. In addition to incorporating the conventional temperature-dependent DOP decomposition, we improve this process by accounting for the effects of dissolved inorganic phosphorus (DIP) and dissolved inorganic nitrogen (DIN) on DOP utilization, based on well-established relationships among these variables. The improved model well reproduces nutrient dynamics observed during the incubations. Simulation results further indicate that DOP utilization can contribute up to 80% of bioavailable P in DIP-deficient environments. Without this process, DIP concentrations would decrease by over 50% within 2 - 5 days, leading to a 20% - 60% decrease in chlorophyll a concentration and an approximately 100% increase in P turnover time. Moreover, the DOP-to-DIP conversion efficiency (i.e., DOP utilization rate) exhibits substantial spatiotemporal variability in surface seawater, with rates as high as 0.1 day
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