Teaching copolymerization catalysis to metal-organic frameworks by confining molecular catalysts in lattices.

• Tác giả: Chao-Yu Chiu, Wen-Yang Gao, Chia-Her Lin, Zhuorigebatu Tegudeer, Chen-Yen Tsai, Pei-Wen Wu
• Ngôn ngữ: eng
• Ký hiệu phân loại: 577.144 *Carbon cycle
• Thông tin xuất bản: England : Chemical communications (Cambridge, England) , 2025
• Bộ sưu tập: NCBI
• ID: 676180

Tóm tắt

Copolymerization catalysis remains underexplored compared to the broad range of other catalytic reactions promoted by metal-organic frameworks (MOFs). Here, we report a lattice-confinement strategy that immobilizes a highly active molecular complex within MOFs, transforming them into effective heterogeneous catalysts for copolymerization-that couples cyclohexene oxide and CO