Stimuli-Responsive Multifunctional Iridium(III) Complex Exhibiting Thermo-, Vapochromism, and Double Catalytic Activity.

• Tác giả: Stanislav I Bezzubov, Paulina Kalle, Marina A Kiseleva, Sergey A Kozyukhin, Sofia S Mariasina, Ekaterina V Nykhrikova, Sergei V Tatarin
• Ngôn ngữ: eng
• Ký hiệu phân loại: 155.911 Influence of sensory stimuli
• Thông tin xuất bản: United States : Inorganic chemistry , 2025
• Bộ sưu tập: NCBI
• ID: 676183

Tóm tắt

Multifunctional compounds with properties that may be triggered by different external stimuli are highly desirable yet challenging in their design and synthesis. Herein, we report a cyclometalated iridium(III) complex based on bulky 1,2-diphenylphenanthroimidazole (C^N) that can easily change its molecular geometry from trigonal-bipyramidal to octahedral or from a monomeric to dimeric state in response to external stimuli (temperature and solvent variations). The extensive characterization including variable-temperature