Spectroscopic and Computational Interrogation of a High-Valent Nickel-Dialkyl Complex Indicates Electronic Structure Asymmetry Drives C-C Bond Formation Reactivity.

• Tác giả: Leonel Griego, Liviu M Mirica, Yusuff Moshood, Hannah S Shafaat, Alina Yerbulekova
• Ngôn ngữ: eng
• Ký hiệu phân loại: 639.2 Commercial fishing, whaling, sealing
• Thông tin xuất bản: United States : Journal of the American Chemical Society , 2025
• Bộ sưu tập: NCBI
• ID: 676312

Tóm tắt

The study of high-valent organometallic nickel compounds has gained considerable interest recently, primarily driven by the development of nickel-catalyzed alkyl-alkyl cross-coupling reactions that are proposed to employ such high-valent intermediates. In that regard, we have recently reported a formal Ni(III)-dimethyl intermediate supported by the ligand