Global Spectral Analysis of Polaritonic Coupling of Multiple Organic Dyes to a Tunable Fabry-Pérot Resonator Operating with Mirror Separations up to 10 µm.

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Tác giả: Jakob Keck, Christoph Kertzscher, Michael Mauch, Alfred J Meixner

Ngôn ngữ: eng

Ký hiệu phân loại: 624.17713 Structural engineering and underground construction

Thông tin xuất bản: Germany : Chemistry (Weinheim an der Bergstrasse, Germany) , 2025

Mô tả vật lý:

Bộ sưu tập: NCBI

ID: 676504

We study strong optical coupling and the formation of hybrid polaritons by a donor-acceptor pair of J-aggregated dyes separated by up to 11 µm in a tunable Fabry-Pérot resonator. Fitting a phenomenological Hamiltonian to the white light transmission spectra of different cavity-J-aggregate-configurations, for which several hundred spectra were recorded sequentially as function of cavity length, allows us to determine coupling energies as a function of the effective cavity distances. The theoretical analysis shows that certain hybrid polaritons contain contributions from both dyes, making this system a promising platform for polariton-mediated energy transfer at very large distances.
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