Kondo-like behavior in a mixed valent oxypnictide La

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Tác giả: Tomasz Klimczuk, Szymon Królak, Soohyeon Shin, Michał J Winiarski, Duygu Yazici

Ngôn ngữ: eng

Ký hiệu phân loại: 231.04 Special topics of God

Thông tin xuất bản: England : Scientific reports , 2025

Mô tả vật lý:

Bộ sưu tập: NCBI

ID: 681956

We have synthesized and characterized the physical properties of a layered, mixed valent oxypnictide [Formula: see text] via magnetization, electrical resistivity, and specific heat measurements. Although [Formula: see text] does not exhibit superconductivity down to T = 0.5 K, it demonstrates an intriguing resistivity minimum observed at [Formula: see text] = 13.7 K. Disappearance of the resistivity minimum under an applied magnetic field of [Formula: see text]H = 9 T together with the negative magnetoresistance at low and positive at high temperatures are observed, which are typical for both Kondo-like spin-dependent scattering and 3D weak localization. We argue that the Kondo scattering is a more plausible explanation due to the low-temperature deviation from the Curie-Weiss law observed in the magnetic susceptibility, consistent with the presence of magnetic interactions between paramagnetic [Formula: see text] ions and Kondo screening of these [Formula: see text] moments. We supplemented the experimental characterization with a detailed description of chemical bonding, employing density functional theory (DFT) calculations and crystal orbital Hamilton population (COHP) analysis for [Formula: see text] and isostructural [Formula: see text], which is a superconductor with [Formula: see text] K. Based on the calculations performed, we present the difference between [Formula: see text] and [Formula: see text] in the character of electronic states at the Fermi level. This discrepancy impacts structural stability and may cause a lack of superconductivity in [Formula: see text] down to T = 0.5 K.
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