Electrocatalysis, which leverages renewable electricity, has emerged as a cornerstone technology in the transition toward sustainable energy and chemical production. However, traditional electrocatalytic systems often produce mixed, impure products, necessitating costly purification. Solid-state electrolyte (SSE) reactors represent a transformative advancement by enabling the direct production of high-purity chemicals, significantly reducing purification costs and energy consumption. The versatility of SSE reactors extends to applications such as CO