Stability and Controlled Polymerization of Trithiocarbonate Chain Transfer Agents Under Harsh Conditions.

• Tác giả: Tomoya Nishimura, Yu Osaki, Toyohiro Otani, Thi Ngan Vu, Shin-Ichi Yusa
• Ngôn ngữ: eng
• Ký hiệu phân loại: 271.6 *Passionists and Redemptorists
• Thông tin xuất bản: Switzerland : Polymers , 2025
• Bộ sưu tập: NCBI
• ID: 68461

Tóm tắt

This study investigates the stability and application of trithiocarbonate-based chain transfer agents (CTAs) in reversible addition-fragmentation chain transfer (RAFT) radical polymerization under harsh conditions. We evaluated the stability of 4-cyano-4-(2-carboxyethylthiothioxomethylthio) pentanoic acid (Rtt-17) and 4-cyano-4-(dodecylsulfanylthiocarbonyl) sulfanylpentanoic acid (Rtt-05) at 60 °C under basic conditions using