Electron Shuttling in High-Valent Heterobimetallic NiFe-Porphyrin Dimers: Stabilization of Ni(III) and Fe-Phenoxyl Radicals.

• Tác giả: Pragya Arora, Nidhi Awasthi, Sayantani Banerjee, Apparao Draksharapu, Nityananda Dutta, Eugenio Garribba, Sankar Prasad Rath, Arya Roychowdhury, Deepannita Samanta
• Ngôn ngữ: eng
• Thông tin xuất bản: United States : Inorganic chemistry , 2025
• Bộ sưu tập: NCBI
• ID: 685010

Tóm tắt

A series of axially phenoxide-bound Ni(II)-Fe(III) heterobimetallic porphyrin dimers, as a synthetic mimic of the diheme enzyme MauG, have been synthesized, which upon 4e