Exploiting Photohalide Generation in Shape and Multichromatic Color Patterning of Polymer-Perovskite Nanocomposites.

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Tác giả: James Chambers, Christopher Cueto, Todd Emrick, Dhimitraq Nikolla, Alexander Ribbe

Ngôn ngữ: eng

Ký hiệu phân loại: 949.59012 *Greece

Thông tin xuất bản: United States : Journal of the American Chemical Society , 2025

Mô tả vật lý:

Bộ sưu tập: NCBI

ID: 685194

The ability to arrange brightly fluorescent nanoscale materials into well-defined patterns is critically important in advanced optoelectronic structures. Traditional methods for doing so generally involve depositing different color quantum dot "inks," irradiating reactive (e.g., cross-linkable) ligands at their surface, and then lifting off the unexposed sections in a developer solvent. Here, we outline a fundamentally different approach for directly patterning the emission color of nanocomposite thin films utilizing mask-based lithographic techniques and laser scanning methods. In this system, a polymer film containing cesium lead halide nanocrystals (NCs) is embedded with an organohalide─termed a "photohalide generator"─which undergoes a light-triggered, perovskite-catalyzed reduction and release of halide anion for uptake by the NC lattice, markedly shifting its band gap. In this manner, a blue emitting (CsPbBr
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