Deciphering the Role of Crown-ether Receptor Orientation in C-H Oxidation Catalyzed by Supramolecular Nonheme Fe

• Tác giả: Giorgio Capocasa, Stefano Di Stefano, Alessandro Fagnano, Federico Frateloreto, Osvaldo Lanzalunga, Leonardo Latini, Stefano Levi Mortera, Giorgio Olivo
• Ngôn ngữ: eng
• Ký hiệu phân loại: 797.123 Rowing
• Thông tin xuất bản: Germany : Chemistry (Weinheim an der Bergstrasse, Germany) , 2025
• Bộ sưu tập: NCBI
• ID: 689240

Tóm tắt

The outstanding efficiency and selectivity of enzymatic reactions, such as C-H oxidation by nonheme iron oxygenases, stems from a precise control of substrate positioning inside the active site. The resulting proximity between a specific moiety (a certain C-H bond) and the reactant (a Fe