Oxidative Neutralisation of Sulfur-Based Chemical Warfare Agents Mediated by a Lipase: From Batch to Flow Reactor.

• Tác giả: Valmir Baptista da Silva, Maxime Boddaert, Julien Legros, Sergui Mansour, Jean-Christophe M Monbaliu, Pierre-Yves Renard, Daniela Vuluga
• Ngôn ngữ: eng
• Ký hiệu phân loại: 583.67 *Ebenales, Primulales, Diapensiales, Thymelaeales (mezereum order)
• Thông tin xuất bản: Germany : Chemistry (Weinheim an der Bergstrasse, Germany) , 2025
• Bộ sưu tập: NCBI
• ID: 689429

Tóm tắt

The sulfur-containing chemical warfare agents sulfur mustard HD and nerve agent VX are highly toxic and persistent in the environment. Therefore, their neutralisation requires harsh oxidation conditions, but also precise selectivity. Here we report the safe and effective detoxification of surrogates CEES and PhX by selective oxidation of the sulfur atom by generating peracetic acid from AcOEt and aq. H