On the structure of nanoparticle clusters: effects of long-range interactions.

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Tác giả: Ankur D Bordoloi, Rens Kamphorst, Gabrie M H Meesters, Samir Salameh, Maximilian F Theisen, J Ruud van Ommen

Ngôn ngữ: eng

Ký hiệu phân loại: 331.714 Managerial occupations

Thông tin xuất bản: England : Physical chemistry chemical physics : PCCP , 2025

Mô tả vật lý:

Bộ sưu tập: NCBI

ID: 689856

The fractal structure of aggregates consisting of primary nanoparticles naturally arises during their synthesis. While typically considered to be a fully stochastic process, we suspect long-range interactions, in particular van der Waals forces, to induce an active pull on particles, altering the clustering process. Using an off-grid 3D model, we show that an active pull decreases the density and fractal dimension of formed clusters. These findings could not be reproduced by 2D models, which underestimate screening effects. Additionally, we determined the range within which van der Waals forces dominate the aggregation process.
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