Enhanced Efficiency and Stability of Tin Halide Perovskite Solar Cells Through MOF Integration.

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Tác giả: Azhar Alowasheeira, Fanyue Kong, Boyuan Li, Lin Li, Ho Ngoc Nam, Quan Manh Phung, Baoning Wang, Yusuke Yamauchi, Yongqi Yin, Kuina Yuan, Xisheng Zhang

Ngôn ngữ: eng

Ký hiệu phân loại:

Thông tin xuất bản: Germany : Small (Weinheim an der Bergstrasse, Germany) , 2025

Mô tả vật lý:

Bộ sưu tập: NCBI

ID: 689896

Tin halide perovskites are promising candidates for lead-free perovskite solar cells due to their ideal bandgap and high charge-carrier mobility. However, poor crystal quality and rapid degradation in ambient conditions severely limit their stability and practical applications. This study demonstrates that incorporating UiO-66, a zirconium-based MOF, significantly enhances the performance and stability of tin halide perovskite solar cells (TPSCs). The unique porous structure and abundant carboxylate groups of UiO-66 improve the crystallinity and film quality of FASnI₃, reduce defect density, and prolong charge carrier lifetimes. Consequently, the power conversion efficiency (PCE) of UiO-66-integrated TPSCs increases from 11.43% to 12.64%, and the devices maintain over 90% of their initial PCE after 100 days in a nitrogen glovebox. These findings highlight the potential of UiO-66 in addressing the efficiency and stability challenges of tin halide perovskites.
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