2D electronically conductive porous coordination polymers/metal-organic frameworks (2D EC-MOFs) of M-HHTPs (HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene
M = Co, Ni, Cu, etc.) have received extensive attention due to their ease of preparation, semiconductive properties, and tunability based on the choice of metal species. However, slight shifts between layers attenuate their specific surface area and stability. In this study, the metal-ion bridge strategy is newly adopted and a vanadyl counterpart of M-HHTP is synthesized with a chemical formula of (VO)