Hard carbon, the Li-free anode for hybrid Li-ion/metal batteries (LIB/LMBs), has great potential for enhancing fast charging capability, energy density, and battery lifespan. However, low initial Coulombic efficiency (ICE) and Li dendrite growth are crucial factors constraining its development. In this work, graphitized layers encapsulated carbon nanofibers (G-CF) are fabricated via Joule heating within 10 s. The C