Probing soft X-ray induced photoreduction of a model Mn-complex at cryogenic conditions.

• Tác giả: Kuntal Chatterjee, Margaret D Doyle, Li Cheng Kao, Jan F Kern, Sang Jun Lee, Stephen R Leone, Charles J Titus, Philippe Wernet, Vittal K Yachandra, Junko Yano
• Ngôn ngữ: eng
• Thông tin xuất bản: United States : Journal of synchrotron radiation , 2025
• Bộ sưu tập: NCBI
• ID: 690560

Tóm tắt

Soft X-ray absorption spectroscopy of first row transition elements at their respective L-edges provides important information about the oxidation and spin states of the metal centers. However, the associated sample damage in radiation-sensitive samples substantially alters the electronic and chemical structures of redox-active metal centers. Here, we measure the soft X-ray spectrum of the model Mn