Design, synthesis, and biological evaluation of 5'-deoxy (N)-methanocarbanucleoside derivatives as A

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Tác giả: Vikas R Aswar, Lak Shin Jeong, Misuk Joung, Minjae Kim, Seung Woo Kim, Siddhi D Naik, Yun A Yum

Ngôn ngữ: eng

Ký hiệu phân loại:

Thông tin xuất bản: England : Bioorganic & medicinal chemistry letters , 2025

Mô tả vật lý:

Bộ sưu tập: NCBI

ID: 690919

Based on the potent and selective antagonism exhibited by truncated North (N)-methanocarba adenosine analogs, we synthesized a series of 5'-deoxy (N)-methanocarba nucleosides to explore their structure-activity relationships (SAR). The stereoselective synthesis of the North cyclopropyl-fused alcohol was achieved from d-ribose using ring-closing metathesis, oxidative rearrangement, and cyclopropanation as key steps. Mitsunobu reactions were employed to condense nucleobases with glycosyl donors, followed by N
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