Multigram Scale Synthesis of Mechanically-Interlocked Derivatives of SWNT using Mechanochemical Methods.

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Tác giả: David M Jiménez, Alejandro López-Moreno, María Luisa Ruiz-González, Alicia Naranjo, Henrik Pedersen, Emilio M Pérez, Marisol Rivas-Caramés, Julia Villalva

Ngôn ngữ: eng

Ký hiệu phân loại:

Thông tin xuất bản: Germany : Chemistry (Weinheim an der Bergstrasse, Germany) , 2025

Mô tả vật lý:

Bộ sưu tập: NCBI

ID: 691633

The grinding of chemical reagents enables mixing, promotes molecular collisions, and provides the thermal energy required for chemical reactions, while reducing the need for solvent (often to none) and significantly speeding up reactions. This has made mechanochemistry a powerful alternative to traditional solution chemistry. Here, we show that mechanically interlocked derivatives of single-walled carbon nanotubes (MINTs) can be made via mechanochemistry in a multigram scale. Compared to the previously reported method in suspension, mechanochemistry allows us to reduce the amount of solvent by two orders of magnitude and the reaction time from 72 h to 5 min. The mechanochemical synthesis of MINTs is proven to work both with purified (6,5)-SWNTs and affordable Tuball
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