Lithium-sulfur (Li/S) batteries are emerging as a next-generation energy storage technology due to their high theoretical energy density and cost-effectiveness. π-Conjugated organosulfur polymers, such as poly(4-(thiophene-3-yl)benzenethiol) (PTBT), have shown promise in overcoming challenges such as the polysulfide shuttle effect by providing a conductive framework and enabling sulfur copolymerization. In these cathodes, cation-π interactions significantly influence Li