Ligand-to-Metal Charge Transfer Controls the Photophysical Properties and HER Activity of Ag

• Tác giả: Abir De Sarkar, Aarti Devi, Amitava Patra, Rashi, Harshita Seksaria
• Ngôn ngữ: eng
• Ký hiệu phân loại: 001.434 Experimental method
• Thông tin xuất bản: United States : The journal of physical chemistry letters , 2025
• Bộ sưu tập: NCBI
• ID: 692484
• Chủ đề: 1. Ligand; 2. To; 3. Metal

Tóm tắt

The hydrogen evolution reaction (HER) activity of ligand-protected metal nanoclusters (NCs) has been emphasized, where the ligands influence the electronic properties and hydrogen adsorption energy during the catalytic process. Here, we highlight the influence of the ligand-to-metal charge transfer (LMCT) on the photoluminescence (PL) properties and the adsorption free energy on the HER activity of Ag