The motion of catalytically active colloids approaching a surface.

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Tác giả: Ali Azadbakht, Mehrad Babaei, Silvana A Caipa Cure, Joost de Graaf, Tom M J Evers, Daniela J Kraft, Alireza Mashaghi, Julio Melio, Solenn Riedel

Ngôn ngữ: eng

Ký hiệu phân loại: 668.1 Surface-active agents (Surfactants)

Thông tin xuất bản: England : Soft matter , 2025

Mô tả vật lý:

Bộ sưu tập: NCBI

ID: 693953

Catalytic microswimmers typically swim close to walls due to hydrodynamic and/or phoretic effects. The walls in turn are known to affect their propulsion, making it difficult to single out the contributions that stem from particle-based catalytic propulsion only, thereby preventing an understanding of the propulsion mechanism. Here, we use acoustic tweezers to lift catalytically active Janus spheres away from the wall to study their motion in bulk and when approaching a wall. Mean-squared displacement analysis shows that diffusion constants at different heights match with Faxén's prediction for the near-wall hydrodynamic mobility. Both particles close to a substrate and in bulk show a decrease in velocity with increasing salt concentration, suggesting that the dominant factor for the decrease in speed is a reduction of the swimmer-based propulsion. The velocity-height profile follows a hydrodynamic scaling relation as well, implying a coupling between the wall and the swimming speed. The observed speed reduction upon addition of salt matches expectations from a electrokinetic theory, except for experiments in 0.1 wt% H
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