Transformation of Zirconium Metal-Organic Cages to Metal-Organic Gels.

• Tác giả: Songliang Cai, Pei Lai, Lai-Yi Li, Liang-Hua Wu, Yu-Wei Zhang, Sheng-Run Zheng
• Ngôn ngữ: eng
• Thông tin xuất bản: United States : Inorganic chemistry , 2025
• Bộ sưu tập: NCBI
• ID: 694262

Tóm tắt

Zirconium metal-organic cages (Zr-MOCs) that assemble from zirconocence-based clusters and carboxylate-based ligands have been widely used as building blocks for constructing various MOC-based materials with diverse applications because of their high stability and solubilities. However, in this work, we found that the structures of a series of Zr-MOCs are quite flexible when heated at 60 °C in an