Changing the form of the electric field in the electric field-assisted aerobic composting (EAC) system from direct current to alternating current is confirmed as a potential strategy to enhance compost humification to the level of hyperthermophilic composting. This study pioneered the comparative evaluation of the effects of different electric field forms on the immobilization and phytotoxicity of heavy metals during composting. The results demonstrated that the humic acid content and humification index of alternating electric field-assisted aerobic composting (AEFAC) were approximately 22.0 % and 33.7 % higher than that of EAC, respectively. Morphometric analysis of various HMs (Cu, Zn, Cr, Cd, and Pb) revealed that the amounts in the exchangeable and reducible fractions were obviously lower in AEFAC than in EAC. AEFAC reduced the bioavailability of multiple HMs to about 15.11-40.21 %, indicating the higher passivation efficiency of several HMs than EAC. PLS-PM analysis indicated that AEFAC inhibited HMs bioavailability mainly through physicochemical properties, humification parameters, and microbial communities. Phytotoxicity experiments confirmed that AEFAC improves the growth indicators of cultivated crops, resulting in a 26.2 % increase in plant height and a 36.2 % increase in root length compared to EAC. Moreover, compared with EAC, AEFAC reduces the accumulation of Cu, Zn, Cr, Cd, and Pb in cultivated plants by approximately 27.0 %, 30.9 %, 32.2 %, 8.6 %, and 10.9 %, respectively. This study provides the first proof of principle that AEFAC effectively promotes the passivation of HMs, providing a practical strategy for efficient and environmentally friendly compost disposal.