Tailoring foaming behavior of poly(lactic acid) by different geometric sizes of bio-based polyamide.

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Tác giả: Jingbo Chen, Youjin He, Junji Hou

Ngôn ngữ: eng

Ký hiệu phân loại:

Thông tin xuất bản: Netherlands : International journal of biological macromolecules , 2025

Mô tả vật lý:

Bộ sưu tập: NCBI

ID: 695966

Naturally derived materials have attracted much attention owing to the demand of sustainability. In this work, bio-based polyamide was used to tailor the foaming behavior of poly(lactic acid) by dispersing into different geometric sizes. The results showed that both micro-sized spherical and fibrillar polyamide markedly shortened the half-crystallization time of poly(lactic acid) in isothermal crystallization process, while nanofibrils played a better role on promoting crystallization than submicron spheres. When the polyamide was in a fibrillar state, the blends exhibited a higher complex viscosity in low frequency region. With increasing frequency, the blend containing nanofibrils displayed an obvious disentanglement phenomenon. Regarding foaming, the micro-sized polyamide particles with larger diameter were more conducive to cell nucleation than that with smaller size. The nanofibrils led to the highest cell density of 1.46 × 10
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