Probing cage dynamics in concentrated hard-sphere suspensions and glasses with high frequency rheometry.

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Tác giả: Thanasis Athanasiou, Baicheng Mei, George Petekidis, Kenneth S Schweizer

Ngôn ngữ: eng

Ký hiệu phân loại:

Thông tin xuất bản: England : Soft matter , 2025

Mô tả vật lý:

Bộ sưu tập: NCBI

ID: 698662

The cage concept, a central microscopic mechanism for glassy dynamics, has been utilized in concentrated colloidal suspensions to describe a number of phenomena. Here, we probe the evolution of cage formation and shear elasticity with increasing volume fraction in hard sphere suspensions, with emphasis on the short-time dynamics. To this end, we utilize linear viscoelastic (LVE) measurements, by means of conventional rotational rheometers and a home-made HF piezo-rheometer, to probe the dynamic response over a broad range of volume fractions up to the very dense glassy regime in proximity to random close packing. We focus on the LVE spectra and times shorter than those corresponding to the dynamic shear modulus
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