Ligand-Assisted Colloidal Synthesis of Alkali Metal-Based Ternary Chalcogenide: Nanostructuring and Phase Control in Na-Cu-S System.

• Tác giả: Nilotpal Kapuria, Hannah McKeever, Adair Nicolson, Kevin M Ryan, David Scanlon, Suvodeep Sen, Shalini Singh
• Ngôn ngữ: eng
• Ký hiệu phân loại: 378.242 Thesis and dissertation requirements
• Thông tin xuất bản: United States : Nano letters , 2025
• Bộ sưu tập: NCBI
• ID: 698725
• Chủ đề: 1. Ligand; 2. Assisted; 3. Colloidal

Tóm tắt

The development of sustainable and tunable materials is crucial for advancing modern technologies. We present a controlled synthesis of colloidal Na-Cu-S nanostructures. To overcome the reactivity difference between Na and Cu precursors toward chalcogens in a colloidal synthesis and to achieve metastable phase formation, we designed a single-source precursor for Cu and S. The decomposition of this precursor creates a Cu-S template into which Na ions diffuse to form metastable Na-Cu-S. By leveraging the reactivity of sulfur precursors, we synthesized Na