Photoaging is common and represents one of the primary pathways for hair damage in daily life. Hydrolyzed keratin, which is usually derived from wool and consists of a series of polypeptide molecules, has been investigated as a UV damage prevention ingredient for hair care. Scanning Electron Microscopy (SEM) and fluorescent penetration experiments verified that hydrolyzed keratin can deposit on the hair cuticles to form a film and partly penetrate into the hair cortex. This film played as a UV reducer and helped hair resist surface damage and maintain a sleek and healthy morphology after UV radiation. Surprisingly, it was found that hydrolyzed keratin treatment combined with subsequent UV radiation could significantly improve the tensile properties of hair. For hydrolyzed-keratin-treated hair, tensile strength was maintained after UV radiation, while, as a comparison, it decreased by 14.32% for untreated hair. This phenomenon is explained by a UV-induced degradation-penetration mechanism. During UV radiation, an increase in free amino acid content and conductivity was observed for the hydrolyzed keratin solution, demonstrating photodegradation into smaller peptides and amino acids. The degradation of hydrolyzed keratin allowed it to more easily enter the interior of the hair cortex, thereby enhancing its tensile properties by enhancing the chemical bonds.