Friction surfacing (FS) is a solid-state process for depositing metallurgically bonded coatings for corrosion and wear protection. It is particularly attractive for depositing coatings in materials that are difficult to fusion deposit. Stellite 6 is one such material, which is widely used as a protective coating on steel structures to combat wear and corrosion. In the current study, Stellite 6 was successfully friction-surfaced on low carbon steel plates without using any preheating. The microstructures and wear behavior of Stellite 6 coatings produced using FS were comparatively investigated with those produced using the plasma transferred arc (PTA) process. The PTA coatings showed a cast microstructure consisting of γ-dendrites and an inter-dendritic carbide network. On the other hand, the FS coatings showed a wrought microstructure with dynamically recrystallized grains and fine, uniformly distributed carbide particles. The FS coatings also showed uniform composition across the coating thickness and were undiluted, while the PTA coatings showed significant dilution as well as strong local variations in chemistry. The FS coatings exhibited a 22% increase in hardness (550 HV) compared to the PTA coatings (450 HV). Pin-on-disc dry sliding wear tests showed that the FS coatings (1.205 mm