At present, the improvement of anti-wear performance of piston rings remains a challenge. In this article, Ni-SiC composite coatings fabricated at 3, 9, and 15 g/L SiC were denoted as NSc-3, NSc-9, and NSc-15 coatings. Meanwhile, the influence of SiC concentration on the surface morphology, phase structure, microhardness, and anti-wear performance of electrodeposited Ni-SiC composite coatings were investigated utilizing scanning electron microscopy, X-ray diffraction, a microhardness tester, and a friction-wear tester, respectively. The SEM images presented NSc-9 coatings with a compact, flat, or cauliflower-like surface morphology. The cross-sectional morphology and EDS results showed that the Si and Ni elements were uniformly distributed in the NSc-9 coatings with dense and flat microstructures. Moreover, the average grain size of the NSc-9 coatings was only 429 nm. Furthermore, the microhardness and indentation path of the NSc-9 coatings were 672 Hv and 13.7 μm, respectively. Also, the average friction coefficient and worn weight loss of the NSc-9 coatings were 0.46 and 29.5 mg, respectively, which were lower than those of the NSc-3 and NSc-15 coatings. In addition, a few shallow scratches emerged on the worn surfaces of the NSc-9 coatings, demonstrating their outstanding anti-wear performance when compared to the NSc-3 and NSc-15 coatings.