The shaping process is recognized as a crucial step in the manufacturing of green tea. However, its influence on aroma quality remains unclear. In this study, the effects of four shaping techniques, including flat green tea (FGT), straight green tea (SGT), phoenix green tea (PGT), and curled green tea (CGT), on the aroma quality and volatile metabolites of green tea were investigated by gas chromatography electronic nose (GC-E-Nose) and gas chromatography-tandem mass spectrometry (GC-MS/MS). The findings indicated that distinct shaping processes significantly influenced the development of the aroma quality and aroma components of green tea. The PGT processing facilitated the attainment of superior aroma quality of green tea. In total, 60 volatile components were identified by GC-MS/MS, with 54 of these compounds being consistently detected across four different shaping techniques. In particular, the PGT processing method was effective in yielding elevated levels of alcohols, esters and ketones. Moreover, 20 key odorants were screened out, with (