Spin excitations in nanographene-based antiferromagnetic spin-1/2 Heisenberg chains.

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Tác giả: Gonçalo Catarina, Roman Fasel, Xinliang Feng, Joaquín Fernández-Rossier, Mar Ferri-Cortés, João C G Henriques, Ji Ma, Carlo A Pignedoli, Pascal Ruffieux, Lin Yang, Chenxiao Zhao

Ngôn ngữ: eng

Ký hiệu phân loại:

Thông tin xuất bản: England : Nature materials , 2025

Mô tả vật lý:

Bộ sưu tập: NCBI

ID: 712534

Antiferromagnetic Heisenberg chains exhibit two distinct types of excitation spectrum: gapped for integer-spin chains and gapless for half-integer-spin chains. However, in finite-length half-integer-spin chains, quantization induces a gap, requiring precise control over sufficiently long chains to study its evolution. Here we create length-controlled spin-1/2 Heisenberg chains by covalently linking Olympicenes-Olympic-ring-shaped magnetic nanographenes. With large exchange interactions, tunable lengths and negligible magnetic anisotropy, this system is ideal for investigating length-dependent spin excitations, probed via inelastic electron tunnelling spectroscopy. We observe a power-law decay of the lowest excitation energy with length L, following a 1/L dependence in the large-L regime, consistent with theory. For L = 50, a V-shaped excitation continuum confirms a gapless behaviour in the thermodynamic limit. Additionally, low-bias current maps reveal the standing wave of a single spinon in odd-numbered chains. Our findings provide evidence for the realization of a one-dimensional analogue of a gapless spin liquid within an artificial graphene lattice.
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