Amorphous nitride semiconductors with highly tunable optical and electronic properties: the benefits of disorder in Ca-Zn-N thin films.

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Tác giả: Stefan Böhm, Maximilian Christis, Johanna Eichhorn, Gabriel Grötzner, Frans Munnik, Ian D Sharp, Elise Sirotti, Verena Streibel, Martin Stutzmann, Laura I Wagner, Lukas Wolz

Ngôn ngữ: eng

Ký hiệu phân loại:

Thông tin xuất bản: England : Materials horizons , 2025

Mô tả vật lý:

Bộ sưu tập: NCBI

ID: 716072

Semiconducting ternary nitrides are a promising class of materials that have received increasing attention in recent years, but often show high free electron concentrations due to the low defect formation energies of nitrogen vacancies and substitutional oxygen, leading to degenerate n-type doping. To achieve non-degenerate behavior, we now investigate a family of amorphous calcium-zinc nitride (Ca-Zn-N) thin films. By adjusting the metal cation ratios, we demonstrate band gap tunability between 1.4 and 2.0 eV and control over the charge carrier concentration across six orders of magnitude, all while maintaining high mobilities between 5 and 70 cm
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