Late 3d metals such as iron, cobalt, nickel, and copper are abundantly present in the Earth's crust and they are produced in huge quantities in the mining industry. Often, these inexpensive metals exhibit unique or special reactivities in catalytic reactions as compared with expensive noble metals such as palladium, iridium, and rhodium. The novel reactivities of 3d metal complexes originate from their unique physical and atomic properties as compared with heavier 4d/5d congeners: smaller ionic and covalent radii, contracted 3d orbitals of smaller sizes and lower energies, lower values of Pauli electronegativity,