Zirconium modified biochar fiber with balanced phosphorus adsorption efficiency and recyclability: A detailed study on the mechanisms of attenuation of adsorption capacity.

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Tác giả: Yanfang Feng, Shiying He, Ruiqian Liu, Siqi Liu, Lihong Xue, Yingjie Zhao

Ngôn ngữ: eng

Ký hiệu phân loại:

Thông tin xuất bản: England : Environmental pollution (Barking, Essex : 1987) , 2025

Mô tả vật lý:

Bộ sưu tập: NCBI

ID: 717691

In the realm of phosphorus (P) adsorption, balancing adsorption capacity and recyclability is crucial. We propose a novel approach by integrating functional metal (Zr) with one-dimensional (1DL) biochar fiber to create P adsorbents. Three synthesis methods-impregnation-pyrolysis, co-precipitation, and hydrothermal synthesis-are evaluated for their effects on P adsorption performances. 1DL adsorbents prepared by impregnation-pyrolysis achieve about 100% of P removal at low concentrations (1.1-5.6 mg-P/L), outperforming 0D powdered and 3D porous granular counterparts. The usage cost of the prepared 1D adsorbent (including the preparation and regeneration costs) is 44.8% of commercial Phoslock® after 10 cycles. Noteworthy is our effort in delving into the mechanisms underpinning capacity attenuation during the regeneration of the P adsorbent-a facet scarcely explored in antecedent inquiries. Long-term applications over 60 days demonstrate the cost-effectiveness and low ion leaching toxicity of the 1DL adsorbent. This study not only advances adsorbent synthesis but also underscores 1DL adsorbents as a promising option for P removal and recovery.
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