Cis/Trans Isomeric Valence Tautomeric Compounds with Guest-Driven Conformational Adaptation in Pillar[5]arene Structures.

• Tác giả: Jie-Sheng Hu, Jun Tao, Meng Yu, Hua-Liang Yue, Ling-Tai Yue, Yu-Meng Zhao
• Ngôn ngữ: eng
• Ký hiệu phân loại: 582.1 Herbaceous and woody plants, plants noted for their flowers
• Thông tin xuất bản: United States : Inorganic chemistry , 2025
• Bộ sưu tập: NCBI
• ID: 717807

Tóm tắt

The pursuit of ancillary ligands is crucial for constructing new valence tautomeric (VT) complexes based on the dioxolene-cobalt(II/III) moiety. In this study, we adopted pillar[5]arene derivatives with guest-adaptable conformations─specifically, phenylpyridine-containing pillar[5]arene (pyphp[5]) and alkynylpyridine-containing pillar[5]arene (pyetp[5])─as ancillary and bridging ligands to synthesize a series of cobalt-based VT complexes: [Co