Tuning Decomposition Temperature: A Structural Study of Ligand Directed Bonding and Fluxionality.

• Tác giả: Abil E Aliev, Kersti Karu, Caroline E Knapp, Shreya Mrig, Salma Saeed, Petra Vasko
• Ngôn ngữ: eng
• Thông tin xuất bản: Germany : Chemistry (Weinheim an der Bergstrasse, Germany) , 2025
• Bộ sưu tập: NCBI
• ID: 722942

Tóm tắt

 In the first study of its kind towards the design and synthesis of easy-to-handle aluminium precursors that decompose at temperatures <
 200 °C: informed ligand choice and structural design of the compounds has caused inbuilt fluxionality leading to a markable decrease in the onset of decomposition temperatures. Eight thiourea ligands [L