Changing the absolute configuration of atropisomeric bisnaphthols (BINOLs).

• Tác giả: Yun Wu, Can Zhu
• Ngôn ngữ: eng
• Ký hiệu phân loại: 579.2569 *Viruses and subviral organisms
• Thông tin xuất bản: England : Chemical communications (Cambridge, England) , 2025
• Bộ sưu tập: NCBI
• ID: 725847

Tóm tắt

Bisnaphthol (BINOL) is a ubiquitous core skeleton in versatile chiral catalysts and ligands for transition metals, and this representative atropisomeric structure also serves as a building block in various optically active natural products. Due to the high rotational barrier (∼40 kcal mol