Synthesis and redox behavior of Si-Si dimeric 9-methylsilafluorene.

• Tác giả: George Q Jiang, Rebekka S Klausen, Andrew Molino, Maxime A Siegler, V Sara Thoi, Kelsie E Wentz, David J D Wilson
• Ngôn ngữ: eng
• Ký hiệu phân loại: 335.4344 Marxian systems
• Thông tin xuất bản: England : Dalton transactions (Cambridge, England : 2003) , 2025
• Bộ sưu tập: NCBI
• ID: 726057

Tóm tắt

Lithium-halogen exchange on 2,2'-dibromo-1,1'-biphenyl followed by salt metathesis with 1,1,2,2-tetrachloro-1,2-dimethyldisilane produced the Si-Si linked dimeric 9-methylsilafluorene (1) in 62% yield. Compound 1 was characterized in the solid state