Global attention to microplastics (MPs) pollution has been increasing as it has become a novel environmental issue. Natural aging processes alter MPs surface properties, introducing charged functional groups that affect their transport in porous media. This study investigated the transport of polystyrene microplastics (PSMPs) in saturated porous media through column experiments, including non-functionalized PSMPs (PS-Bare), carboxyl-modified PSMPs (PS-COOH), and amino-modified PSMPs (PS-NH